Oxidation of monohydric and dihydric alcohols with CCl4 catalyzed by molybdenum compounds

…, RY Burangulova, ZS Muslimov, UM Dzhemilev

Index: Khusnutdinov; Shchadneva; Burangulova; Muslimov; Dzhemilev Russian Journal of Organic Chemistry, 2006 , vol. 42, # 11 p. 1615 - 1621

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Citation Number: 4

Abstract

Abstract Mo (CO) 6 catalyzed oxidation of alcohols and diols with tetrachloromethane. Primary oxidation products in reaction of alcohols with CCl 4 are alkyl hypochlorites, and final products depending on the structure of initial alcohol are aldehydes (as acetals), ketones, chloroketones, and esters.

Detail

~89%

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~97%

~0%

~98%

~2%

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~95%

~72%

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