e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Synthesis of the sym-Triazine System. II. 1 Preparation of Monosubstituted sym-Triazines by Reaction of sym-Triazine with Amidines

FC Schaefer, GA Peters

Index: Schaefer; Peters Journal of the American Chemical Society, 1959 , vol. 81, p. 1470,1473

Full Text: HTML

Citation Number: 22

Abstract

678 (1935). discloses the reaction of I with aniline which produces N, N'- diphenylformamidine. Grundmann and Ratz3 and, independently, Dr. Hechenbleikner in our laboratory have also shown the reaction of sym-triazine with ammonium chloride to be very clean and to lead to formamidine hydrochloride in essentially quantitative yield. Application of this degradation reaction for the preparation of such heterocyclic formamidines as ...

N-(1-Amino-2,2,2-trichloroethylidene)-2,2,2-trichloroethanimidamide Structure

N-(1-Amino-2,2,...

~%

1,3,5-Triazine,2,4,6-tris(trichloromethyl)- Structure

1,3,5-Triazine,...

N-(1-Amino-2,2,2-trichloroethylidene)-2,2,2-trichloroethanimidamide Structure

N-(1-Amino-2,2,...

~%

4,6-bis(trichloromethyl)-1,3,5-triazin-2-amine Structure

4,6-bis(trichlo...

1,3,5-Triazine,2,4,6-tris(trichloromethyl)- Structure

1,3,5-Triazine,...

s-triazine Structure

~%

2-methoxy-1,3,5-triazine Structure

2-methoxy-1,3,5...

s-triazine Structure

~%

2-benzyl-1,3,5-triazine Structure

2-benzyl-1,3,5-...

2,4-dibenzyl-[1,3,5]triazine Structure

2,4-dibenzyl-[1...

s-triazine Structure

6-ALPHA-FLUORO-ISOFLUPREDONE Structure

6-ALPHA-FLUORO-...

~%

2-(trichloromethyl)-1,3,5-triazine Structure

2-(trichloromet...

s-triazine Structure

6-ALPHA-FLUORO-ISOFLUPREDONE Structure

6-ALPHA-FLUORO-...

Acetonitrile Structure

~%

2-(trichloromethyl)-1,3,5-triazine Structure

2-(trichloromet...

Detail

Benzimidamide hydrochloride Structure

Benzimidamide h...

Formimidamide hydrochloride Structure

Formimidamide h...

~%

Phenyl-1,3,5-triazine Structure

Phenyl-1,3,5-tr...

2,4-Diphenyl-1,3,5-triazine Structure

2,4-Diphenyl-1,...

s-triazine Structure

Benzamidine Structure

~%

Phenyl-1,3,5-triazine Structure

Phenyl-1,3,5-tr...

2,4-Diphenyl-1,3,5-triazine Structure

2,4-Diphenyl-1,...

s-triazine Structure

3-Nitrobenzenecarboximidamide Structure

3-Nitrobenzenec...

~%

2-(3-nitrophenyl)-1,3,5-triazine Structure

2-(3-nitropheny...

s-triazine Structure

Phenylguanidinecarbonate Structure

Phenylguanidine...

~%

N-phenyl-1,3,5-triazin-2-amine Structure

N-phenyl-1,3,5-...

s-triazine Structure

~%

2-methylsulfanyl-1,3,5-triazine Structure

2-methylsulfany...

Formimidamide hydrochloride Structure

Formimidamide h...

Propionimidamide hydrochloride Structure

Propionimidamid...

~%

2,4-diethyl-1,3,5-triazine Structure

2,4-diethyl-1,3...

Tributylamine suppliers in China Structure

Tributylamine s...

Formimidamide hydrochloride Structure

Formimidamide h...

~%

s-triazine Structure

s-triazine Structure

acetamidine Structure

~%

2,4-dimethyl-1,3,5-triazine Structure

2,4-dimethyl-1,...

s-triazine Structure

Methanol Structure

acetamidine Structure

~%

2,4-dimethyl-1,3,5-triazine Structure

2,4-dimethyl-1,...

Methanol Structure

Formimidamide hydrochloride Structure

Formimidamide h...

acetamidine Structure

~%

2-methyl-1,3,5-triazine Structure

2-methyl-1,3,5-...

Detail

acetamidine Structure

~%

2,4,6-trimethyl-1,3,5-triazine Structure

2,4,6-trimethyl...

Acetonitrile Structure

Methanol Structure

Formimidamide hydrochloride Structure

Formimidamide h...

acetamidine Structure

~%

2-methyl-1,3,5-triazine Structure

2-methyl-1,3,5-...

Detail

s-triazine Structure

Acetimidamide hydrochloride Structure

Acetimidamide h...

~%

2-methyl-1,3,5-triazine Structure

2-methyl-1,3,5-...

s-triazine Structure

acetamidine Structure

~%

2-methyl-1,3,5-triazine Structure

2-methyl-1,3,5-...

s-triazine Structure

Methanol Structure

acetamidine Structure

~%

2-methyl-1,3,5-triazine Structure

2-methyl-1,3,5-...

Methanol Structure

Formimidamide hydrochloride Structure

Formimidamide h...

acetamidine Structure

~%

2-methyl-1,3,5-triazine Structure

2-methyl-1,3,5-...

Detail

2,2,2-trichloroethanimidamide Structure

2,2,2-trichloro...

~%

4,6-bis(trichloromethyl)-1,3,5-triazin-2-amine Structure

4,6-bis(trichlo...

N-(1-Amino-2,2,2-trichloroethylidene)-2,2,2-trichloroethanimidamide Structure

N-(1-Amino-2,2,...

~%

4,6-bis(trichloromethyl)-1,3,5-triazin-2-amine Structure

4,6-bis(trichlo...

N-(1-Amino-2,2,2-trichloroethylidene)-2,2,2-trichloroethanimidamide Structure

N-(1-Amino-2,2,...

~%

4,6-bis(trichloromethyl)-1,3,5-triazin-2-amine Structure

4,6-bis(trichlo...

1,3,5-Triazine,2,4,6-tris(trichloromethyl)- Structure

1,3,5-Triazine,...

2,2,2-trichloroethanimidamide Structure

2,2,2-trichloro...

~%

1,3,5-Triazine-2,4-diamine,6-(trichloromethyl)- Structure

1,3,5-Triazine-...

Chloroform Structure

4,6-bis(trichloromethyl)-1,3,5-triazin-2-amine Structure

4,6-bis(trichlo...

Detail

2,2,2-trichloroethanimidamide Structure

2,2,2-trichloro...

~%

1,3,5-Triazine-2,4-diamine,6-(trichloromethyl)- Structure

1,3,5-Triazine-...

Chloroform Structure

4,6-bis(trichloromethyl)-1,3,5-triazin-2-amine Structure

4,6-bis(trichlo...

Detail

2,2,2-trichloroethanimidamide Structure

2,2,2-trichloro...

~%

1,3,5-Triazine-2,4-diamine,6-(trichloromethyl)- Structure

1,3,5-Triazine-...

Chloroform Structure

4,6-bis(trichloromethyl)-1,3,5-triazin-2-amine Structure

4,6-bis(trichlo...

Detail

N-(1-Amino-2,2,2-trichloroethylidene)-2,2,2-trichloroethanimidamide Structure

N-(1-Amino-2,2,...

Benzamidine Structure

~%

4-phenyl-6-(trichloromethyl)-1,3,5-triazin-2-amine Structure

4-phenyl-6-(tri...

A new synthesis of ethyl trifluoroacetate

[Norton Journal of the American Chemical Society, 1950 , vol. 72, p. 3527]