Angewandte Chemie (International Edition) 2007-01-01

A remarkably efficient fluoroalkylation of cyclic sulfates and sulfamidates with PhSO2CF2H: facile entry into beta-difluoromethylated or beta-difluoromethylenated alcohols and amines.

Chuanfa Ni, Jun Liu, Laijun Zhang, Jinbo Hu

Index: Angew. Chem. Int. Ed. Engl. 5th ed., 46 , 786-789, (2007)

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Structure	Name/CAS No.	Molecular Formula	Articles
	[(Difluoromethyl)sulfonyl]benzene CAS:1535-65-5	C₇H₆F₂O₂S

Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, ...
2008-08-01
[J. Org. Chem. 15th ed., 73 , 5699-5713, (2008)]

Preparation of tri- and difluoromethylsilanes via an unusual...
2003-05-30
[J. Org. Chem. 11th ed., 68 , 4457-4463, (2003)]

Facile synthesis of chiral alpha-difluoromethyl amines from ...
2005-09-12
[Angew. Chem. Int. Ed. Engl. 36th ed., 44 , 5882-5886, (2005)]

Nucleophilic difluoromethylation of primary alkyl halides us...
2004-11-11
[Org. Lett. 23th ed., 6 , 4315-4317, (2004)]

Stereoselective synthesis of di- and monofluoromethylated vi...
2007-04-13
[J. Org. Chem. 8th ed., 72 , 3119-3121, (2007)]