Chemical Communications 2012-07-04

NTCDA-TTF first axial fusion: emergent panchromatic, NIR optical, multi-state redox and high optical contrast photooxidation.

Deepak Asthana, M R Ajayakumar, Rajendra Prasad Pant, Pritam Mukhopadhyay

Index: Chem. Commun. (Camb.) 48(52) , 6475-7, (2012)

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Abstract

The first synthetic entry into axially fused NTCDA/PMDA-TTF multipolar molecules demonstrates a high optical contrast photooxidation, panchromism, low HOMO-LUMO gap, generation of a stable radical cation, NIR absorption/emission beyond 2150/800 nm and theoretically calculated NLO activity.