649. The kinetics and mechanisms of addition to olefinic substances. Part III. The carbonium ionic intermediate involved in addition of hypochlorous acid to iso butene

PBD de La Mare, A Salama

Index: de la Mare; Salama Journal of the Chemical Society, 1956 , p. 3337,3342,3344

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Citation Number: 7

Abstract

Addition of hypochlorous acid to isobutene in water gives mainly l-chloro-2-methylpropan-2- ol; the chief olefinic by-product is 3-chloro-2-methylpropene. The latter olefin is also the predominant by-product in the hydrolysis in water of 1: 2-dichloro-2-methylpropane.

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