Synlett

Structure and Reactivity of Bis (iodozincio) methane in Tetrahydrothiophene

S Matsubara, Y Yamamoto, K Utimoto

Index: Matsubara, Seijiro; Yamamoto, Yuhei; Utimoto, Kiitiro Synlett, 1999 , # 9 p. 1471 - 1473

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Citation Number: 10

Abstract

Abstract: Addition of tetrahydrothiophene (THT) to a THF solution of bis (iodozincio) methane modified the stability and reactivity: EXAFS analysis indicated that THT stabilizes bis (iodozincio) methane in a monomeric structure; the species reacts with acyl chlorides to give 1, 3-diketones. Key words: zinc, 1, 3-diketone, dimetal, THT, EXAFS

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