Tetrahedron letters

A comparison of the decomposition of a 3-nitreno-1, 3-oxazolin-2-one and the isomeric 1, 3, 4-oxadiazin-2-one

RM Wilson, TJ Chow

Index: Wilson, R. Marshall; Chow, Tahsin J. Tetrahedron Letters, 1983 , vol. 24, # 43 p. 4635 - 4636

Full Text: HTML

Citation Number: 2

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The oxidation of 3-amino-4,5-diphenyl-1,3-oxazolin-2-one ( ) affords monodiazobenzil as the primary decomposition product of -nitrolactam . In contrast, the oxidation 3,6-dihydro-5,6-diphenyl -1,3,4-oxadiazin-2-one ( ) leads to diphenylacetylene ( ) via oxadiazin-2-one .

 Related Synthetic Route
3-amino-4,5-diphenyl-1,3-oxazol-2-one Structure

88485-01-2

3-amino-4,5-dip...

~70%

desyl chloride Structure

447-31-4

desyl chloride

3-amino-4-hydroxy-4,5-diphenyl-1,3-oxazolidin-2-one Structure

88485-00-1

3-amino-4-hydro...

~%

desyl chloride Structure

447-31-4

desyl chloride

3-amino-4,5-diphenyl-1,3-oxazol-2-one Structure

88485-01-2

3-amino-4,5-dip...

~60%

Ethanone, 2-diazo-1,2-diphenyl- Structure

3469-17-8

Ethanone, 2-dia...

3-amino-4-hydroxy-4,5-diphenyl-1,3-oxazolidin-2-one Structure

88485-00-1

3-amino-4-hydro...

~%

Ethanone, 2-diazo-1,2-diphenyl- Structure

3469-17-8

Ethanone, 2-dia...

4,5-Diphenyl-1,3-dioxol-2-one Structure

21240-34-6

4,5-Diphenyl-1,...

~%

5-hydroxy-5,6-diphenyl-1,3,4-oxadiazinan-2-one Structure

88484-99-5

5-hydroxy-5,6-d...

3-amino-4-hydroxy-4,5-diphenyl-1,3-oxazolidin-2-one Structure

88485-00-1

3-amino-4-hydro...

4,5-Diphenyl-1,3-dioxol-2-one Structure

21240-34-6

4,5-Diphenyl-1,...

~%

5-hydroxy-5,6-diphenyl-1,3,4-oxadiazinan-2-one Structure

88484-99-5

5-hydroxy-5,6-d...

3-amino-4-hydroxy-4,5-diphenyl-1,3-oxazolidin-2-one Structure

88485-00-1

3-amino-4-hydro...

3-amino-4-hydroxy-4,5-diphenyl-1,3-oxazolidin-2-one Structure

88485-00-1

3-amino-4-hydro...

~%

3-amino-4,5-diphenyl-1,3-oxazol-2-one Structure

88485-01-2

3-amino-4,5-dip...

3-amino-4-hydroxy-4,5-diphenyl-1,3-oxazolidin-2-one Structure

88485-00-1

3-amino-4-hydro...

~%

4,5-diphenyl-3-(propan-2-ylideneamino)-1,3-oxazol-2-one Structure

88485-03-4

4,5-diphenyl-3-...

3-amino-4,5-diphenyl-1,3-oxazol-2-one Structure

88485-01-2

3-amino-4,5-dip...

Acetone Structure

67-64-1

Acetone

~%

4,5-diphenyl-3-(propan-2-ylideneamino)-1,3-oxazol-2-one Structure

88485-03-4

4,5-diphenyl-3-...

5-hydroxy-5,6-diphenyl-1,3,4-oxadiazinan-2-one Structure

88484-99-5

5-hydroxy-5,6-d...

~%

5,6-diphenyl-3,6-dihydro-1,3,4-oxadiazin-2-one Structure

19836-49-8

5,6-diphenyl-3,...


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