Photo??fluorodecarboxylation of 2??Aryloxy and 2??Aryl Carboxylic Acids

…, JG West, M Rueda??Becerril, JF Paquin…

Index: Leung, Joe C. T.; Chatalova-Sazepin, Claire; West, Julian G.; Rueda-Becerril, Montserrat; Paquin, Jean-Francois; Sammis, Glenn M. Angewandte Chemie - International Edition, 2012 , vol. 51, # 43 p. 10804 - 10807 Angewandte Chemie, 2012 , vol. 124, # 43 p. 10962 - 10965

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Citation Number: 74

Abstract

The escalating importance of fluorinated compounds in the pharmaceutical and agrochemical sectors has placed a premium on the development of novel synthetic methods for fluorine incorporation.[1] In that respect, we have recently demonstrated that the electrophilic fluorine sources N-fluorobenzenesulfonimide (NFSI)[2] and Selectfluor [3] can effectively fluorinate alkyl radicals.[4] Continuing research in this direction motivated us to ...