Conversions of 2-Phenyl-1, 3, 2-dioxaphospholane Under the Action of Hydrogen Chloride

SN Lazarev, ZA Bredikhina, AA Bredikhin

Index: Lazarev; Bredikhina; Bredikhin Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 928 - 932

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Abstract

Abstract The reaction of 2-phenyl-1, 3, 2-dioxaphospholane with HCl gives a mixture of phenylphosphinic acid, bis (2-chloroethyl) phenylphosphonate, and phenylphosphine; therewith, intermediate oligomeric phosphonites, hydrophosphoryl compounds, and phosphoranes were detected. Thermal treatment of the reaction mixture results in formation of ethylene phenylphosphonate and (2-chloroethyl) phenylphosphinate.