The Journal of Organic Chemistry

Preparation of methyl ketones by the sequential treatment of carboxylic acids with methyllithium and chlorotrimethylsilane

GM Rubottom, C Kim

Index: Journal of Organic Chemistry, , vol. 48, # 9 p. 1550 - 1552

Full Text: HTML

Citation Number: 112

Abstract

... George M. Rubottom* and Chong-wan Kim Department of Chemistry, University of Idaho, Moscow, Idaho 83843 Received August 23, 1982 ... Pays-Bas 1946, 65, 1607; and other references cited in ref 1. (4) (a) House, H. 0.; Bare, TM 'Organic Syntheses"; Wiley: New York ... J. Org. ...

 Related Synthetic Route
n-heptanoic acid Structure

111-14-8

n-heptanoic acid

METHYLLITHIUM Structure

917-54-4

METHYLLITHIUM

~7%

2-Octanol, 2-methyl- Structure

628-44-4

2-Octanol, 2-methyl-

2-Octanone Structure

111-13-7

2-Octanone

n-Butyllithium Structure

109-72-8

n-Butyllithium

1-Hexanoic acid Structure

142-62-1

1-Hexanoic acid

~73%

5-Methyldecan-5-ol Structure

87258-26-2

5-Methyldecan-5-ol

5-Decanone Structure

820-29-1

5-Decanone

n-heptanoic acid Structure

111-14-8

n-heptanoic acid

METHYLLITHIUM Structure

917-54-4

METHYLLITHIUM

~91%

2-Octanol, 2-methyl- Structure

628-44-4

2-Octanol, 2-methyl-

2-Octanone Structure

111-13-7

2-Octanone

METHYLLITHIUM Structure

917-54-4

METHYLLITHIUM

benzoic acid Structure

65-85-0

benzoic acid

~%

α-Cumyl alcohol Structure

617-94-7

α-Cumyl alcohol

Acetophenone Structure

98-86-2

Acetophenone

METHYLLITHIUM Structure

917-54-4

METHYLLITHIUM

Cyclohexanecarboxylic acid Structure

98-89-5

Cyclohexanecarb...

~90%

1,1-Dimethylcyclohexylmethanol Structure

16664-07-6

1,1-Dimethylcyc...

1-Cyclohexylethan-1-one Structure

823-76-7

1-Cyclohexyleth...


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