Design, synthesis and insecticidal activity of novel phenylpyrazoles containing a 2, 2, 2-trichloro-1-alkoxyethyl moiety

Q Zhao, Y Li, L Xiong, Q Wang

Index: Zhao, Qiqi; Li, Yongqiang; Xiong, Lixia; Wang, Qingmin Journal of Agricultural and Food Chemistry, 2010 , vol. 58, # 8 p. 4992 - 4998

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Citation Number: 42

Abstract

A series of novel phenylpyrazoles containing a 2, 2, 2-trichloro-1-alkoxyethyl moiety were designed and synthesized via the key intermediate 5-trichloroethylideneimino-3-cyano-1-(2, 6-dichloro-4-trifluoromethylphenyl)-4-alkylsulfenylpyrazole (5). The addition reaction of the imine 5 was closely related with the nature of the alcohol. The target compounds were confirmed by 1H NMR and elemental analysis. The results of bioassays indicated that the ...