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e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Synlett

Efficient heterogeneous palladium-montmorillonite catalysts for Heck coupling of aryl bromides and chlorides

Á Molnár, A Papp

Index: Molnar, Arpad; Papp, Attila Synlett, 2006 , # 18 p. 3130 - 3134

Full Text: HTML

Citation Number: 9

Abstract

Abstract New palladium catalysts were prepared using ion exchange or intercalation of Pd species into montmorillonite. The catalysts promote Heck reaction of various aromatic halides including aryl chlorides to give coupling products in high yields at low catalyst ratios down to 0.001 mol%.

 Related Synthetic Route
phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

4-Iodoanisole Structure

696-62-8

4-Iodoanisole

~0%

Benzene,1-methoxy-4-(1-phenylethenyl)- Structure

4333-75-9

Benzene,1-metho...

Benzene,1-methoxy-4-[(1E)-2-phenylethenyl]- Structure

1694-19-5

Benzene,1-metho...

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

4-Bromoanisole Structure

104-92-7

4-Bromoanisole

~0%

Benzene,1-methoxy-4-(1-phenylethenyl)- Structure

4333-75-9

Benzene,1-metho...

Benzene,1-methoxy-4-[(1E)-2-phenylethenyl]- Structure

1694-19-5

Benzene,1-metho...

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

1-(4-Chlorophenyl)ethanone Structure

99-91-2

1-(4-Chlorophen...

~0%

N/A Structure

20488-43-1

N/A

1-[4-(1-phenylethenyl)phenyl]ethanone Structure

87324-13-8

1-[4-(1-phenyle...

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

4-Bromopyridine Structure

1120-87-2

4-Bromopyridine

~0%

4-(1-phenylethenyl)pyridine Structure

54813-56-8

4-(1-phenylethe...

(E)-4-Styrylpyridine Structure

5097-93-8

(E)-4-Styrylpyridine

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

4-Bromochlorobenzene Structure

106-39-8

4-Bromochlorobenzene

~0%

(E)-1-(4-Chlorophenyl)-2-phenylethene Structure

1657-50-7

(E)-1-(4-Chloro...

1-(1-(4-CHLOROPHENYL)VINYL)BENZENE Structure

18218-20-7

1-(1-(4-CHLOROP...

Bromobenzene Structure

108-86-1

Bromobenzene

acrylic acid methyl ester Structure

292638-85-8

acrylic acid me...

~81%

METHYL 2-PHENYLACRYLATE Structure

1865-29-8

METHYL 2-PHENYL...

Methyl cinnamate Structure

103-26-4

Methyl cinnamate

Bromobenzene Structure

108-86-1

Bromobenzene

acrylic acid methyl ester Structure

292638-85-8

acrylic acid me...

~0%

METHYL 2-PHENYLACRYLATE Structure

1865-29-8

METHYL 2-PHENYL...

Methyl cinnamate Structure

103-26-4

Methyl cinnamate

phenylene-ethylene Structure

292638-84-7

phenylene-ethylene

Chlorobenzene Structure

108-90-7

Chlorobenzene

~0%

diphenylethylene Structure

530-48-3

diphenylethylene

diphenylethylene Structure

103-30-0

diphenylethylene

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Detail Synthetic Route


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