Bulletin of the Chemical Society of Japan

Nickel-catalyzed dehydrogenation of amines to nitriles

S Yamazaki, Y Yamazaki

Index: Yamazaki Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 1 p. 301 - 303

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Citation Number: 55

Abstract

Aliphatic primary amines having α-methylene underwent oxidative dehydrogenation on treatment with NiSO 4 as a catalyst and K 2 S 2 O 8 as an oxidant to give the corresponding nitriles in good yields. Benzhydrylamine was converted to benzhydrylideneamine quantitatively under the same reaction conditions.

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