Chloroarylation and thiocyanatoarylation of itaconic acid

VS Baranovskii, BM Petrushka, AY Fesak…

Index: Baranovskii; Petrushka; Fesak; Grishchuk Russian Journal of General Chemistry, 2013 , vol. 83, # 2 p. 325 - 328 Zh. Obshch. Khim., 2013 , vol. 83, # 2 p. 271 - 274,4

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Abstract

Abstract Under conditions of Meerwein reaction and anionarylation the aryldiazonium salts and itaconic acid form 2-chloro (thiocyanato)-2-benzylbutanedioic acids as the chloro-and thiocyianatoarylation products. The reaction is not accompanied by the decarboxylation process and other transformations affecting the carboxy groups of itaconic acid.