Journal of Hazardous Materials 2014-07-30

Cu-TiO2 nanorods with enhanced ultraviolet- and visible-light photoactivity for bisphenol A degradation.

Li-Fen Chiang, Ruey-An Doong

Index: J. Hazard. Mater. 277 , 84-92, (2014)

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Abstract

In this study, the microwave-assisted sol-gel method and chemical reduction were used to synthesize Cu-TiO2 nanorod composites for enhanced photocatalytic degradation of bisphenol A (BPA) in the presence of UV and visible lights. The electron microscopic images showed that the Cu nanoparticles at 4.5±0.1nm were well-deposited onto the surface of TiO2 nanorods after chemical reduction of Cu ions by NaBH4. The X-ray diffractometry patterns and X-ray photoelectron spectroscopic results indicated that Cu species on the Cu-TiO2 nanorods were mainly the mixture of Cu2O and Cu(0). The Cu-TiO2 nanorods showed excellent photocatalytic activity toward BPA photodegradation under the irradiation of UV and visible lights. The pseudo-first-order rate constant (kobs) for BPA photodegradation by 7wt% Cu-TiO2 nanorods were 18.4 and 3.8 times higher than those of as-synthesized TiO2 nanorods and Degussa P25 TiO2, respectively, under the UV light irradiation. In addition, the kobs for BPA photodegradation by 7wt% Cu-TiO2 nanorods increased by a factor of 5.8 when compared with that of Degussa P25 TiO2 under the irradiation of 460±40nm visible light. Results obtained in this study clearly demonstrate the feasibility of using one-dimensional Cu-TiO2 nanorods for photocatalytic degradation of BPA and other pharmaceutical and personal care products in water and wastewater treatment plants. Copyright © 2014 Elsevier B.V. All rights reserved.