Luminescence 2015-08-01

Determination of ethanol using permanganate-CdS quantum dot chemiluminescence system.

Jafar Abolhasani, Javad Hassanzadeh

Index: Luminescence 30 , 660-7, (2015)

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Abstract

A novel and highly sensitive chemiluminescence (CL) method for the determination of ethanol was developed based on the CdS quantum dots (QDs)-permanganate system. It was found that KMnO4 could directly oxidize CdS QDs in acidic media resulting in relatively high CL emission. A possible mechanism was proposed for this reaction based on UV/Vis absorption, fluorescence and the generated CL emission spectra. However, it was observed that ethanol had a remarkable inhibition effect on this system. This effect was exploited in the determination of ethanol within the concentration range 12-300 µg/L, with detection at 4.3 µg/L. In order to evaluate the capability of presented method, it was satisfactorily utilized in the determination of alcohol in real samples.Copyright © 2014 John Wiley & Sons, Ltd.