The Journal of Physical Chemistry

A comparative study of organic counterion binding to micelles with the Fourier transform NMR self-diffusion technique

M Jansson, P Stilbs

Index: Jansson, Mikael; Stilbs, Peter Journal of Physical Chemistry, 1985 , vol. 89, # 22 p. 4868 - 4873

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Citation Number: 56

Abstract

Multicomponent NMR self-diffusion measurements on D20 solutions of decylammonium acetate, chloroacetate, and dichloroacetate are reported. The association behavior of ionic surfactant systems, as evaluated for a comparison of individual component diffusion data (quantified in terms of the degree of counterion binding, the cmc, and the nonmicellar amphiphile concentration above the cmc), was found to be distinctly sensitive to the ...