Polyhedron

Synthesis and characterization of organophosphine/phosphite stabilized N-silver (I) succinimide: crystal structure of [(Ph 3 P) 3· AgNC 4 H 4 O 2]

X Tao, YQ Li, HH Xu, N Wang, FL Du, YZ Shen

Index: Tao, Xian; Li, Yue-Qin; Xu, Hui-Hua; Wang, Ning; Du, Fang-Li; Shen, Ying-Zhong Polyhedron, 2009 , vol. 28, # 6 p. 1191 - 1195

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Citation Number: 12

Abstract

Six organophosphine/phosphite stabilized N-silver (I) succinimide complexes of the type Ln· AgNC4H4O2 (L= PPh3; n= 1, 2a; n= 2, 2b; n= 3, 2c; L= P (OEt) 3; n= 1, 2d; n= 2, 2e; n= 3, 2f) have been prepared by reacting [AgNC4H4O2], which can be synthesized from succinimide and excessive Ag2O in boiling water, with triphenylphosphine or triethylphosphite in dichloromethane under a nitrogen atmosphere. These complexes were obtained in high ...