Organometallics

Half-Sandwich Scorpionates as Nitrene Transfer Catalysts

S Liang, MP Jensen

Index: Liang, Lei; Lv, Hongbin; Yu, Yi; Wang, Peng; Zhang, Jun-Long Dalton Transactions, 2012 , vol. 41, # 5 p. 1457 - 1460

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Citation Number: 26

Abstract

Scorpionate complexes of the middle to late 3d transition metals [(L) M (NCMe) 3](BF4) n (M= Mn, Fe, Co, Ni: 1 M, L= tris (3, 5-dimethylpyrazol-1-yl) methane, TpmMe, Me, n= 2; 2 M, L= tris (3-phenylpyrazol-1-yl) methane, TpmPh, n= 2; 3 M except 3 Mn, L= hydrotris (3, 5-