Highly fluorophilic phosphines incorporating at least one aromatic ring containing two directly attached perfluoroalkyl groups have been synthesised, their partition coefficients (organic phase: fluorous phase) measured and their electronic properties probed using 1JPtP data for their trans-[PtCl2L2] complexes. These phosphines have been used as modifying ligands for the rhodium catalysed hydroformylation of 1-octene in ...
![[3,5-bis(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)phenyl]-diphenylphosphane Structure](https://image.chemsrc.com/caspic/117/874161-77-0.png)
