The Journal of Organic Chemistry

Reaction of acyl azide and amines. Kinetics and mechanism

DC Berndt, AL Faburada

Index: Berndt, Donald C.; Faburada, Abraham L. Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4167 - 4169

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Citation Number: 5

Abstract

Kinetic Procedure. Five microliters of a solution of 2-naphthoyl azide in the appropriate solvent was added to a thermostated (25.0 OC) solution of the amine in the appropriate solvent. Approximately 3-4 mL of the mixture was transferred into 1-cm quartz cuvettes in a thermostated (25.0" C) compartment of a Gilford 252 spectrophotometer. The progress of the reaction was monitored by taking absorbance readings for at least