Dalton Transactions

Synthesis, molecular structure, and stability of a zirconocene derivative with α-Keggin mono-aluminum-substituted polyoxotungstate

CN Kato, Y Makino, W Unno, H Uno

Index: Kato, Chika Nozaki; Makino, Yuki; Unno, Wataru; Uno, Hidemitsu Dalton Transactions, 2013 , vol. 42, # 4 p. 1129 - 1135

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Citation Number: 9

Abstract

The synthesis and crystal structure of a zirconocene derivative with α-Keggin mono- aluminum-substituted polyoxotungstate,[α-PW11Al (OH) O39ZrCp2] 26−(Cp= C5H5−)(1), which was obtained by the reaction of α-Keggin mono-aluminum-substituted polyoxotungstate with a biscyclopentadienylzirconium (IV) complex, is described herein. Analytically pure, homogeneous, yellow crystals of the tetra-n-butylammonium salt of ...