Practical conversion of chlorosilanes into alkoxysilanes without generating HCl

R Wakabayashi, Y Sugiura, T Shibue…

Index: Wakabayashi, Ryutaro; Sugiura, Yasushi; Shibue, Toshimichi; Kuroda, Kazuyuki Angewandte Chemie - International Edition, 2011 , vol. 50, # 45 p. 10708 - 10711

Full Text: HTML

Citation Number: 17

Abstract

Alkoxysilanes are used as key starting materials in inorganic, organic, and materials chemistry for sol-gel processes,[1] surface modification (silane coupling agent),[2] protection of hydroxy groups (silyl ether),[3] and cross-coupling reactions (Hiyama coupling).[4] Various alkoxysilanes are industrially produced for diverse purposes. The industrial and classical methods for synthesizing alkoxysilanes are based on the reaction of a chlorosilane and an ...