Pd/Light??Accelerated Atom??Transfer Carbonylation of Alkyl Iodides: Applications in Multicomponent Coupling Processes Leading to Functionalized Carboxylic Acid …

…, T Inouye, K Morimoto, T Fukuyama…

Index: Fusano, Akira; Sumino, Shuhei; Nishitani, Satoshi; Inouye, Takaya; Morimoto, Keisuke; Fukuyama, Takahide; Ryu, Ilhyong Chemistry - A European Journal, 2012 , vol. 18, # 30 p. 9415 - 9422

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Citation Number: 28

Abstract

Abstract The atom-transfer carbonylation reaction of various alkyl iodides thereby leading to carboxylic acid esters was effectively accelerated by the addition of transition-metal catalysts under photoirradiation conditions. By using a combined Pd/hν reaction system, vicinal C- functionalization of alkenes was attained in which α-substituted iodoalkanes, alkenes, carbon monoxide, and alcohols were coupled to give functionalized esters. When alkenyl ...