Gas-phase electron-transfer equilibrium studies on tetraalkylhydrazines: geometry effects on ionization thermochemistry, relaxation energies, and ion solvation …

SF Nelsen, DT Rumack, M Meot-Ner

Index: Nelsen, Stephen F.; Rumack, Daniel T.; Meot-Ner, Michael Journal of the American Chemical Society, 1988 , vol. 110, # 24 p. 7945 - 7952

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Citation Number: 27

Abstract

Abstract: Equilibrium constants for electron-transfer equilibration between 35 pairs of tetraalkylhydrazines and their cation radicals were measured by high-pressure mass spectrometry and provided the data allowing calculation of aIP and ASo of ionization for 3 1 tetraalkylhydrazines. Photoelectron spectroscopy measurements of VIP allow calculation of their enthalpies of relaxation, which range from a highest value of 38.3 kcal/mol for the ...