The Journal of Organic Chemistry

Chemistry of hydrazides. X. The reduction of cyclic and acyclic hydrazides with diborane

H Feuer, F Brown Jr

Index: Feuer,H.; Brown,F. Journal of Organic Chemistry, 1970 , vol. 35, p. 1468 - 1471

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Citation Number: 47

Abstract

1, 2-DialkyI-and 1, 2-diarylperhydropyridazine-3, 6-diones (1) are reduced in high yield to the corresponding 1, 2-dialkyl-and 1, 2-diarylperhydropyridazines (2) on treatment with diborane at 65". Half-reduced 1, 2-di-alkylperhydropyridazin-3-ones (3a-3d) in addition to the fully reduced compounds 2a-2d are obtained if reactions are performed at 25". At higher diborane concentrations (IO equiv) at 65", compounds la-If undergo reduction of the ...