Practical Synthesis of 2??Arylacetic Acid Esters via Palladium??Catalyzed Dealkoxycarbonylative Coupling of Malonates with Aryl Halides

B Song, F Rudolphi, T Himmler…

Index: Advanced Synthesis and Catalysis, , vol. 353, # 9 p. 1565 - 1574

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Citation Number: 7

Abstract

... Advanced Synthesis & Catalysis. ... We evaluated all known protocols in the context of the synthesis of ortho-substituted aryl acetates, which are ... catalyst systems involving commercially available components and inexpensive bases were clearly required to advance this reaction ...

~48%

~16%

~82%

~75%

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