The Journal of organic chemistry

Preparation of nitrogen-containing π-deficient heteroaromatic grignard reagents: oxidative magnesiation of nitrogen-containing π-deficient halogenoheteroaromatics …

O Sugimoto, S Yamada, K Tanji

Index: Sugimoto, Osamu; Sudo, Muneyoshi; Tanji, Ken-Ichi Tetrahedron, 2001 , vol. 57, # 11 p. 2133 - 2138

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Citation Number: 26

Abstract

The oxidative magnesiation of nitrogen-containing π-deficient halogenoheteroaromatics using active magnesium was accomplished. Both magnesiation followed by addition of a carbonyl compound (Grignard reaction) and magnesiation in the presence of a carbonyl