Tetrahedron Letters

Reaction of a triazolinedione with simple alkenes. Isolation and characterization of hydration products

Z Syrgiannis, F Koutsianopoulos, KW Muir, Y Elemes

Index: Syrgiannis, Zois; Koutsianopoulos, Fotios; Muir, Kenneth W.; Elemes, Yiannis Tetrahedron Letters, 2009 , vol. 50, # 3 p. 277 - 280

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Citation Number: 12

Abstract

The reaction of N-phenyltriazolinedione with three simple alkyl-substituted alkenes in water/alcohol or water/acetone solution was found to give a mixture of the corresponding ene and water addition products. The new hydration products were characterized by spectroscopy, and in one case, also by X-ray diffraction analysis. Thermodynamic parameters were determined for the reactions involving 2-methylbut-2-ene, TriME, and 2, ...