Ene reaction of triazolinediones with alkenes. 1. Structure and properties of products

S Ohashi, KW Leong, K Matyjaszewski…

Index: Ohashi, Shinichi; Leong, Koon-wah; Matyjaszewski, Kristoff; Butler, George B. Journal of Organic Chemistry, 1980 , vol. 45, # 17 p. 3467 - 3471

Full Text: HTML

Citation Number: 77

Abstract

RR toward cyclohexene than is ethyl azodicarboxylate. Saville2 used this reaction for cross- linking of natural rubber. We3s4 have successfully used this reaction for modification of polybutadiene, polyisoprene, and copolymers of butadiene and isoprene. However, no systematic studies on this reaction itself have been reported. A study was undertaken to obtain fundamental background information on the ene reaction between TD and alkenes. ...

 Related Synthetic Route
4-Phenyl-1,2,4-triazole-3,5-dione Structure

4233-33-4

4-Phenyl-1,2,4-...

propene Structure

187737-37-7

propene

~55%

4-phenyl-1-prop-2-enyl-1,2,4-triazolidine-3,5-dione Structure

73970-92-0

4-phenyl-1-prop...

cis-2-butene Structure

590-18-1

cis-2-butene

4-Phenyl-1,2,4-triazole-3,5-dione Structure

4233-33-4

4-Phenyl-1,2,4-...

~80%

1-but-3-en-2-yl-4-phenyl-1,2,4-triazolidine-3,5-dione Structure

73970-94-2

1-but-3-en-2-yl...

tetramethylethylene Structure

563-79-1

tetramethylethylene

4-Phenyl-1,2,4-triazole-3,5-dione Structure

4233-33-4

4-Phenyl-1,2,4-...

~88%

1,2,4-Triazolidine-3,5-dione,4-phenyl-1-(1,1,2-trimethyl-2-propen-1-yl)- Structure

64891-99-2

1,2,4-Triazolid...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved