Organometallics

Chemistry of heavy carbene analogs R2M (M= Si, Ge, Sn). 12. Concerted and nonconcerted insertion reactions of dimethylgermylene into the carbon-halogen bond

J Koecher, M Lehnig, WP Neumann

Index: Koecher, Juergen; Lehnig, Manfred; Neumann, Wilhelm P. Organometallics, 1988 , vol. 7, p. 1201 - 1207

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Citation Number: 29

Abstract

During the reaction of MezGe with CC13X (X= C1, Br), PhCHzX (X= Br, I), and PhzCHCl,'H CIDNP is observed in the products of net insertion of MezGe into the carbon-halogen bond and in MezGeXz (X= C1, Br). It is concluded that a two-step radical reaction takes place by ...