On the nature of the radical pairs involved in the Grignard reaction

…, OS Akkerman, F Bickelhaupt

Index: Boer, Henricus J. R. de; Akkerman, Otto S.; Bickelhaupt, Friedrich Angewandte Chemie, 1988 , vol. 100, p. 735 - 737

Full Text: HTML

Citation Number: 32

Abstract

During the simultaneous reaction of alkyl bromides and of p-halosubstituted benzyl bromides with magnesium in THF/C6D6 (1: 4), CIDNP net effects (emission) are observed in the 1H nmr spectrum. The effects are opposite to those occurring during the reaction of