Efficient synthesis of N-substituted pyrroles catalyzed by a novel an organic–inorganic hybrid solid acid catalyst

L Gao, L Bing, Z Zhang, H Kecheng, H Xiaoyun…

Index: Gao, Lanchang; Bing, Liu; Zhang, Zehui; Kecheng, Huang; Xiaoyun, Hu; Deng, Kejian Journal of Organometallic Chemistry, 2013 , vol. 735, p. 26 - 31

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Abstract

A novel organic–inorganic hybrid solid acid [MIMBS] 3PW12O40 has been successfully prepared. It showed high catalytic activity for N-substituted pyrroles through the cyclocondensation of primary amines with 1, 4-dicarbonyl compounds. The solid acid catalyst is stable and can be easily recovered and reused without losing its activity in its efficiency. In addition, a plausible mechanism for the catalytic action of [MIMBS] ...