The Journal of Organic Chemistry

Synthesis of 2-methoxyallyl chloride, bromide, and iodide by two independent routes. Reaction of N-halosuccinimides with 2-methoxypropene and the pyrolysis of 1- …

HMR Hoffmann, G Greenwood

Index: Greenwood,G.; Hoffmann,H.M.R. Journal of Organic Chemistry, 1972 , vol. 37, # 4 p. 611 - 617

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Abstract

A portion (1.0 g) of this oil was dissolved with AcnO (2 ml) in dry pyridine (7 ml). After 16 hr the mixture was poured into ice-water, and the resulting mixture was extracted with ether. The ether extract was dried over anhydrous MgSO~, filtered, and evaporated under reduced pressure to give an oil which slowly crystallized on standing. Recrystallization from CHaOH gave the product (0.53 g), mp 115-118'. Another recrystalliza- tion from CH,OH provided an analytical ...