Novel electrocatalytic procedure for the oxidation of alcohols, aldehydes, cyclic ketones, and carbon-hydrogen bonds adjacent to olefinic or aromatic groups

MS Thompson, WF De Giovani, BA Moyer…

Index: Thompson, Mark S.; Giovani, Wagner F. De; Moyer, Bruce A.; Meyer, Thomas J. Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4972 - 4977

Full Text: HTML

Citation Number: 111

Abstract

An analytically pure sample was obtained by preparative GC: bp 108-110 "C (45 mm); IR (CHCI3) 3260,2975, 1385,1264,1077, 1010 cm-'; 'H NMR (CDC13) 6 1.05 (d, 12 H), 3.17 (m, ... (s,4 H), 5.35 (br s, 2 H, exchanged with DzO); 13C NMR (CDCl,) 6 71.8,50.5,19.0; mass spectrum, m/e (relative intensity) 176 (0.30, M+), 161 (16), 104 (28), 102 (77), 76 (6.7), 75 (111, 72 (46), 60 (29), 59 (6.9), 58 (loo), 56 (21). Anal. Calcd for C8HzoNz02: C, 54.52; H, ...