Gas-phase chemistry of the silaformyl anion, HSiO

S Gronert, RAJ O'Hair, S Prodnuk…

Index: Gronert, Scott; O'Hair, Richard A. J.; Prodnuk, Stephen; Suelzle, Detlev; Damrauer, Robert; DePuy, Charles H. Journal of the American Chemical Society, 1990 , vol. 112, p. 998 - 1003

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Citation Number: 38

Abstract

Abstract: The silaformyl anion, HSiO-, has been prepared by collisionally induced dissociation (CID) of H3SiO-in a tandem flowing afterglow selected ion flow tube (FA-SIFT). The chemistry of the silaformyl anion has been studied in detail. Reactions with C02, COS, CS2, SO2, 02, acetic acid, nitromethane, and hexafluorobenzene reveal a rich chemistry. For example, the silaformyl anion reacts with C02 by both an oxidative pathway giving ...