Organic letters

Rhodium-Catalyzed, Efficient Deutero-and Tritiosilylation of Carbonyl Compounds from Hydrosilanes and Deuterium or Tritium

M Rubio, J Campos, E Carmona

Index: Rubio, Miguel; Campos, Jesuus; Carmona, Ernesto Organic Letters, 2011 , vol. 13, # 19 p. 5236 - 5239

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Citation Number: 15

Abstract

A cationic rhodium compound which is an active catalyst for both the hydrogen isotope exchange in hydrosilanes and the hydrosilylation of carbonyl compounds permits, in a one- flask, two-step procedure, efficient deutero-and tritiosilylations using SiEt3H under D2 (0.5 bar) or T2, at low catalyst loadings (0.1–0.5 mol%).

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