Rhodium (II) perfluorobutyrate catalyzed silane alcoholysis. A highly selective route to silyl ethers

MP Doyle, KG High, V Bagheri, RJ Pieters…

Index: Doyle, Michael P.; High, Kenneth G.; Bagheri, Vahid; Pieters, Roland J.; Lewis, Patricia J.; Pearson, Matthew M. Journal of Organic Chemistry, 1990 , vol. 55, # 25 p. 6082 - 6086

Full Text: HTML

Citation Number: 73

Abstract

Rhodium (I1) perfluorobutyrate, Rhz (pfb),, is an effective catalyst for the alcoholysis of trialkylsilanes at room temperature. Primary alcohols react with triethylsilane approximately 5 times faster than do secondary alcohols, and tertiary alcohols are virtually inert. ...

~72%

An efficient synthesis of silyl ethers of primary alcohols, ...

[Sridhar, Madabhushi; Raveendra, Jillella; China Ramanaiah, Beeram; Narsaiah, Chinthala Tetrahedron Letters, 2011 , vol. 52, # 45 p. 5980 - 5982]

Highly Efficient and Chemoselective Ruthenium??Catalyzed Hyd...

[Do, Youngshil; Han, Junghoon; Rhee, Young Ho; Park, Jaiwook Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3363 - 3366]

Rhodium-Catalyzed, Efficient Deutero-and Tritiosilylation of...

[Rubio, Miguel; Campos, Jesuus; Carmona, Ernesto Organic Letters, 2011 , vol. 13, # 19 p. 5236 - 5239]

Selective reduction of carboxylic acids to aldehydes catalyz...

[Bezier, David; Park, Sehoon; Brookhart, Maurice Organic Letters, 2013 , vol. 15, # 3 p. 496 - 499]

A remarkable solvent effect toward the Pd/C-catalyzed cleava...

[Sajiki, Hironao; Ikawa, Takashi; Hattori, Kazuyuki; Hirota, Kosaku Chemical Communications, 2003 , # 5 p. 654 - 655]