Chemistry Letters

Synthesis of (glycolato-O, O′) diammineplatinum (II) and its related complexes

T Totani, K Aono, M Komura, Y Adachi

Index: Totani, Tetsushi; Aono, Katsutoshi; Komura, Michihiro; Adachi, Yasuko Chemistry Letters, 1986 , p. 429 - 432

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Citation Number: 39

Abstract

Glycolatoplatinum (II) complexes,[Pt (OCOCH 2 O) L 2], having a novel five-membered ring structure were obtained by adding an equimolar quantity of glycolic acid to cis-[Pt (OH) 2 L 2](L: NH 3, amines) in water followed by heating. These complexes have also been obtained by reaction of cis-[Pt (NO 3) 2 L 2] with sodium glycolate in neutral aqueous solution. These complexes have been characterized by SIMS, IR, and NMR spectroscopy.