N??Bonded Monosilanols: Synthesis and Characterization of ArN (SiMe3) SiMe2Cl and ArN (SiMe3) SiMe2OH (Ar= C6H5, 2, 6??Me2C6H3, 2, 6??iPr2C6H3)

V Chandrasekhar, R Boomishankar…

Index: Chandrasekhar, Vadapalli; Boomishankar, Ramamoorthy; Azhakar, Ramachandran; Gopal, Kandasamy; Steiner, Alexander; Zacchini, Stefano European Journal of Inorganic Chemistry, 2005 , # 10 p. 1880 - 1885

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Abstract

Abstract By the use of aniline and the sterically hindered aromatic primary amines, 2, 6-Me 2 C 6 H 3 NH 2 and 2, 6-iPr 2 C 6 H 3 NH 2, N-bonded monochlorosilanes, ArN (SiMe 3) SiMe 2 Cl [Ar= C 6 H 5 (1a), Ar= 2, 6-Me 2 C 6 H 3 (1b) and Ar= 2, 6-iPr 2 C 6 H 3 (1c)] have been prepared by a sequential deprotonation at the nitrogen followed by reaction with silyl chlorides. Hydrolysis of the N-bonded monochlorosilanes afforded the N-bonded ...