Chemistry–A European Journal

2, 2??Bis (ethoxycarbonyl) vinyl (BECV) as a Versatile Amine Protecting Group for Selective Functional??Group Transformations

A Ilangovan, RG Kumar

Index: Ilangovan, Andivelu; Kumar, Rajendran Ganesh Chemistry - A European Journal, 2010 , vol. 16, # 9 p. 2938 - 2943

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Citation Number: 17

Abstract

Abstract A 2, 2-Bis (ethoxycarbonyl) vinyl-(BECV) group was used for the selective protection of amines at room temperature in the presence of potentially interfering functional groups such as OH, SH, COOH as well as other NH 2 groups. Several functional group transformations such as esterification, O-alkylation, O-acylation, N-alkylation, N-acylation, S- alkylation can selectively be carried out in the presence of the BECV group. The selective ...

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Selective reduction of nitro compounds with titanium (II) re...

[George, James; Chandrasekaran, S. Synthetic Communications, 1983 , vol. 13, # 6 p. 495 - 500]