Organometallics

Evidence for carbon-oxygen bond formation, aldehyde decarbonylation, and dimerization by reaction of formaldehyde and acetaldehyde with trans-ROIr (CO)(PPh3) 2

KA Bernard, JD Atwood

Index: Organometallics, , vol. 7, p. 235 - 236

Full Text: HTML

Citation Number: 29

Abstract

... Scheme In OR H OAbbreviations: P = PPh,; R = Me, n-Pr, i-Pr, t-Bu; R' = H, Me. ... 1986,308, 361. mitted for publication. Organomet. Chem. 1987,323, 247. 0276-73331881 2307-0235$01.50/ 0 0 1988 American Chemical Society Page 2. 236 Organometallics, Vol. 7, No. 1, 1988 ...

 Related Synthetic Route
trans-n-PrOIr(CO)(PPh3)2 Structure

94070-39-0

trans-n-PrOIr(C...

~%

N/A Structure

17250-59-8

N/A

methyl formate Structure

107-31-3

methyl formate

PROPYL FORMATE Structure

110-74-7

PROPYL FORMATE

N/A Structure

99688-37-6

N/A

~%

N/A Structure

17250-59-8

N/A

methyl formate Structure

107-31-3

methyl formate

trans-t-BuOIr(CO)(PPh3)2 Structure

98720-65-1

trans-t-BuOIr(C...

~%

N/A Structure

17250-59-8

N/A

methyl formate Structure

107-31-3

methyl formate

TERT-BUTYL FORMATE Structure

762-75-4

TERT-BUTYL FORMATE

trans-n-PrOIr(CO)(PPh3)2 Structure

94070-39-0

trans-n-PrOIr(C...

~%

N/A Structure

17250-59-8

N/A

methyl formate Structure

107-31-3

methyl formate

PROPYL FORMATE Structure

110-74-7

PROPYL FORMATE

N/A Structure

94070-38-9

N/A

ch3cho Structure

75-07-0

ch3cho

~%

N/A Structure

17250-59-8

N/A

Methyl acetate Structure

79-20-9

Methyl acetate

Detail
trans-t-BuOIr(CO)(PPh3)2 Structure

98720-65-1

trans-t-BuOIr(C...

~%

N/A Structure

17250-59-8

N/A

methyl formate Structure

107-31-3

methyl formate

TERT-BUTYL FORMATE Structure

762-75-4

TERT-BUTYL FORMATE

N/A Structure

94070-38-9

N/A

ch3cho Structure

75-07-0

ch3cho

~%

N/A Structure

17250-59-8

N/A

Methyl acetate Structure

79-20-9

Methyl acetate

Detail
N/A Structure

94070-38-9

N/A

~91%

N/A Structure

17250-59-8

N/A

methyl formate Structure

107-31-3

methyl formate


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