A series of new 3-amino, 3-aminomethyl-5-alkoxy-3, 4-dihydro-2H-1-benzopyran and 5′- alkoxy-3′, 4′-dihydrospiro [piperazine-2, 3′(2′ H)-benzopyran] derivatives was prepared and evaluated for affinity at 5-HT1A, 5-HT2A and D2 receptors. Two of the compounds (1f and 2b) can be considered as potent and selective 5-HT2A ligands. One compound (1g) demonstrated high affinity for 5-HT1A and D2 receptor binding sites and ...