Journal of the American Chemical Society

The effect of hydrophobic-lipophilic interactions on chemical reactivity. 1. New evidence for intermolecular aggregation and self-coiling

X Jiang, Y Hui, W Fan

Index: Jiang, Xi-Kui; Hui, Yong-Zheng; Fan, Wei-Qiang Journal of the American Chemical Society, 1984 , vol. 106, # 13 p. 3839 - 3843

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Citation Number: 32

Abstract

Abstract: The hydrolytic behavior of 21 para-substituted phenyl esters of n-alkanoic acids (nX) with various chain lengths in 60: 40 (0= 0.60), 5050 (0= 0.50), and 40: 60 v/v (a= 0.40) Me $ O-H20 mixtures was studied. Four new sets of experimental results which include departure from Hammett correlation for n-hexadecanoates (16-X), substantial differences in activation parameters, and effects of amylose on the kinetic parameters and on the ...