Tetrahedron

A new procedure for the preparation of 2-vinylindoles and their [4+ 2] cycloaddition reaction

YAM Mohamed, F Inagaki, R Takahashi, C Mukai

Index: Mohamed, Yaseen Ali Mosa; Inagaki, Fuyuhiko; Takahashi, Ryohei; Mukai, Chisato Tetrahedron, 2011 , vol. 67, # 29 p. 5133 - 5141

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Citation Number: 16

Abstract

Abstract A new approach for the synthesis of 2-vinylindole derivatives by 5-exo mode cyclization of 2-(3-silyloxymethylallenyl) anilines was developed. The starting allenylanilines were easily prepared by the Stille coupling of o-iodoaniline and allenylstannanes. The ...