Hydrazines and azides via the metal-catalyzed hydrohydrazination and hydroazidation of olefins

…, B Gaspar, H Nambu, EM Carreira

Index: Waser, Jerome; Gaspar, Boris; Nambu, Hisanori; Carreira, Erick M. Journal of the American Chemical Society, 2006 , vol. 128, # 35 p. 11693 - 11712

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Citation Number: 201

Abstract

The discovery, study, and implementation of the Co-and Mn-catalyzed hydrohydrazination and hydroazidation reactions of olefins are reported. These reactions are equivalent to direct hydroaminations of CC double bonds with protected hydrazines or hydrazoic acid but are based on a different concept in which the H and the N atoms come from two different reagents, a silane and an oxidizing nitrogen source (azodicarboxylate or sulfonyl azide). ...