Structure and properties of molybdenum (IV, V) arenethiolates with a neighboring amide group. Significant contribution of NH. cntdot.. cntdot.. cntdot. S hydrogen bond …

…, T Okamura, A Nakamura

Index: Ueyama, Norikazu; Okamura, Taka-Aki; Nakamura, Akira Journal of the American Chemical Society, 1992 , vol. 114, # 21 p. 8129 - 8137

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Citation Number: 87

Abstract

V= 3578 (1) AS, Z= 2, and dald= 1.351 g~ m-~. Both complexes have a distorted square- pyramidal structure with an axial Mo= O and two distinct kinds of Mo-S bonds. All four acylamino groups of both complexes are located at the Mo= O side even in spite of the steric neighboring congestion which is similar to the reported structure of (NEt4)[MoVO (SC6H5) 4]. All four NH groups are involved in intraligand NH-4 hydrogen bonds with which ...