Synthesis and structure??activity relationship of several aromatic ketone??based two??photon initiators

…, A Ajami, W Husinsky, A Rosspeintner…

Index: Li, Zhiquan; Siklos, Marton; Pucher, Niklas; Cicha, Klaus; Ajami, Aliasghar; Husinsky, Wolfgang; Rosspeintner, Arnulf; Vauthey, Eric; Gescheidt, Georg; Stampfl, Juergen; Liska, Robert Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 17 p. 3688 - 3699

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Citation Number: 40

Abstract

Abstract Several novel aromatic ketone-based two-photon initiators containing triple bonds and dialkylamino groups were synthesized and the structure-activity relationships were evaluated. Branched alkyl chains were used at the terminal donor groups to improve the solubility in the multifunctional monomers. Because of the long conjugation length and good coplanarity, the evaluated initiators showed large two-photon cross section values, while ...