Israel Journal of Chemistry

Palladium Catalysed Reaction of Myrcene with Acetic Acid and Phenol

S Watanabe, K Suga, K Hijikata

Index: Watanabe,S. et al. Israel Journal of Chemistry, 1971 , vol. 9, p. 273 - 280

Full Text: HTML

Citation Number: 2

Abstract

Abstract This paper concerns the reaction of myrcene, 7-methyl-3-methylene-1, 6-octadiene, with acetic acid-sodium acetate and phenol-sodium phenoxide in the presence of a variety of palladium-catalysts under various conditions. The reaction of myrcene with acetic acid catalysed by palladous chloride-triphenyl phosphine in benzene under nitrogen gave a mixture of linalylacetate (I), 2-acetoxy-3-methylene-7-methyl-6-octene (II), 3-acetoxymethyl ...