Characterization of monomeric thiopivalaldehyde

E Vedejs, DA Perry, RG Wilde

Index: Vedejs, Edwin; Perry, David A.; Wilde, Richard G. Journal of the American Chemical Society, 1986 , vol. 108, # 11 p. 2985 - 2989

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Citation Number: 57

Abstract

Abstract: The title compound is the first aliphatic thioaldehyde to be observed under ordinary laboratory conditions. Its spectral data and chemical characterization are described, including 2+ 3 cycloadditions with nitronate ester 6, 2+ 4 cycloaddition with reactive dienes, thiophilic addition with phenyllithium, carbophilic addition with butyllithium, conversion to episulfide 15 by the Wittig reagent, and oxidation to sulfine 17 with MCPBA. Independent ...